MEDICAL POLLUTION CONTROL COMMITTEE

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You Are in BMW Management Technology >> Hard Technology >> Treatment for Chemical Waste

Treatment for Chemical Waste: 
1. The Bio-Medical Waste suggest chemical treatment for chemical waste streams before final
    disposal.
2. Chemical treatment involves moderate capital and operating cost as compared to other treatment
    options.
3. Waste remains intact after treatment.  Where chlorine compounds are utilized as the disinfectant,

    there is concern regarding the presence of chlorinated organics in the wastewater and subsequent
    management of this waste stream.
4. Well-trained staff is required.
5. Treatment of wastewater is as per the regulatory requirements before final discharge.
6. No volume reduction occurs.
Some of the commonly used disinfectants and recommended concentrations are given below:

Sl  No

Disinfectants

Recommended concentrations/ dilutions 

Light contaminated

Grossly contaminated

1.

Sodium hypochlorite liquid bleach

1 g/L (20 ml/L)

10 g/L (200ml/L)

2.

Calcium hypochlorite

1.4 g/L

14.0 g/L

3.

Sodiumdichloro-isocyannurate (NaDCC) (Available as tablets of 1.5 g)

1.7 g/L

17.0 g/L

4.

Chloramine

20 g/L

20 g/L

5.

Tincture of iodine

2.5%

2.5%

6.

Polyvidone iodine (Povidone iodine (Betadine))

2.5%

2.5%

7.

Glutaraldehyde

2%

2%

8.

Formaldehyde - Formaline

5% (2% formaldehyde)

10% (4% formaldehyde)

9.

Ethyl alcohol

70%

70%

10.

Isopropyl alcohol

70%

70%

11.

Methylated spirit (denatured alcohol)

70%

70%

12.

Hydrogen peroxide

6% (freshly prepared)

Not recommended

13.

Phenol (carbolic acid)

5%

10%

14.

Creson

2.5%

5%

15.

Lyson (saponified cresol)

2.5%

2.5%

16.

Chloroxylenol (4.8% v/v Dettol)

4%

10%

17.

Chloroxylenol (1+0.1%(EDTA))

3%

6%

18.

Chlorhexidine (1.5% v/v Hibitane)

5%

10%

19.

Chlorhexidine + cetrimide (Savlon)

-

-

20.

Ethylene oxide gas

450-800 mg/L

-

Chemical Hazardous Wastes
Waste minimization methods for general medical and surgical hospitals

S. No. Waste Category Waste Minimization Method
1. Chemotherapeutic & Antineoplastics >>Reduce volumes used
>>Optimize drug container sizes in purchasing
>>Return outdated drugs to the manufacturers
>>Centralized chemotherapy compounding location
>>Minimize waste from compounding hood cleaning
>>provide spill clean ups
>>Segregate wastes
2. Formaldehyde >>Minimize strength for formaldehyde solutions
>>Minimize wastes from cleaning dialysis machines and RO units.
>>Use reverse osmosis waster treatment to reduce dialysis cleaning
    demand
>>capture waste formaldehyde
>> Investigate reuse in pathology, autopsy labs
3. Photographic Chemicals >>Return off-spac developer to manufacturer
>>Cover developer and fixes cans to reduce evaporation
>>Recover silver efficiently
>>Recycle waste film and paper
>>Segregate and properly label radioactive wastes and store short lived
    wastes in isolation untill decay permits disposal in trash
>>Substitute less hazardous cleaning agents, methods for solvents
    cleaners
4. Solvents >>Reduce analytic volume requirements
>>Use premixed kits for tests involving solvent fixation
>>Use calibrated solvent dispensers for routine tests
>>Segregate solvent wastes
>> Recover reuse solvents through distillation
5. Mercury >> Substitute electronic sensing devices for mercury containing devices
>>Provide mercury spill cleanup kits and train personnel
>>Recycle uncontaminated mercury wastes using proper safety control 
6. Waste Anesthetic Gases >>Empty low leakage work practices, purchase low leakage equipments, maintain equipment to avoid leakage
7. Toxic, Corrosive and Misc. Chemicals >>Inspection and proper equipment maintenance for ethylene oxide  
    sterilizers
>>Substitute less toxic compounds, cleaning agents
>>Reduce volumes used in experiments
>>Return containers for reuse, use recyclable drums
>>Neutralize acid waste with basic waste
>>Use mechanical handling aids for drums to reduce spills
>>Use automated systems by laundry chemicals
>>Use physical instead of chemical cleaning methods